hi,
sounds like the expansion vessel needs repressurising or replacing. as water heats it expands like anything.the exp vessel is full of air to take up that expanssion.hence if no air in vessel(or poss the hose to it blocked)as the boiler heats the water it expands and pressure increases till it hits 3bar when the pressure relief valve empties the system water outside thus leaving no pressure in the system.
so it does sound like the exp vessel or hose to it could be to blame
ps it is against water bylaws to leave the fill loop connected
(22 yrs working for BGas)
hope this helps a bit
happy14971
November 2010