Boiler operation is such that the HW call has to move the relevant component all the way before boiler sequence is started. With full travel of the diverter valve, CH zone will be isolated. The rad will get some hot water at the end of HW demand due to pump overun (if needed)
If the rads are heating during HW demand, I would suspect a maladjustment of HW call switch or operating beam, sediment related problem, diverter shuttle and even lack of proper service on the boiler. A well made boiler that will last a long time.
DP
May 2005