Sounds like your expansion vessel has gone kaput. You could try re-pressurising it as it may have lost it's pressure. If you look in the manual (on page 54 Linea insallation & servicing instructions if you have it)-when looking at the boiler from above- right at the back is a large whoopee cushion looking thing. This is the expansion vessel. It is designed to take up the increase in presuure as the water in the system gets hot & expands.(A good analagy would be-BUT DON'T TRY THIS- if you sealed the spout on a kettle as it boiled what would happen to the lid with all the steam? It would blow it off. This is what your boiler is trying to avoid by throwing the water through the overflow to stop it exploding) On the top is a car tyre valve-top it up to about 15psi when the boilers cold & not in service. If's it's below give it a go & see how you get along. If it's already got pressre it's probably knackered. Your looking at around £85 just for the part not including fitting.
The reason you keep having to top it back up is because the expansion is not being taken up & the pressure release valve ( a safety part designed to stop a wonky boiler blowing up) starts throwing the water out of the system at 3 bar. Loss of water equals top-up.
You could cut the cost by fitting an auxilillary expansion vessel the look like an orange drum about a foot & a half tall & are a lot cheaper usually than original equipment boiler vessels. a 12 litre one is around £25 with the mounting bracket.
If all this sounds gobledy-gook discuss it with your service engineer.
Hope this helps
Steve
Steve Bedford
November 2007