This is a common problem, google 'Vokera diaphragm excel' etc to find postings.
The 96e manual can be downloaded as a pdf from the Vokera website (www.vokera.co.uk ,literature, discontinued products)
The boiler knows you need hot water when a fulcrum arm is moved when you turn on a hot tap, this operates a microswitch. The most likely cause of your problem is that the arm is not moving because the domestic hot water diaphragm has a hole in it.
You need the manual, look at page 33 for the exploded diagram of this bit of the boiler. Turn off the boiler and disconnect from the electricity, turn of the cold water going in. Remove the case. Remove the fulcrum arm by unscrewing the slot headed pivot screw. Remove the grille below the boiler to improve access (two cross headed screws right & left front) remove the five screws (posidrive/spanner) from the brass cover over the diaphragm. Remove the shot diaphragm and carefully clean off all traces of it left stuck on the plastic pusher plate and the brass insides; this is important, if you don't do this the replacement will not last long. Fit a new diaphragm and re-assemble. If you get drips from where the actuating pin passes through the brass cover you need a new 'o'ring holder guide thing. This is provided as part of service kit t0019, fitted in a standard Vokera service. If this does not fix the problem (it should) then it is possible that the microswitch is faulty, replacement is straightforward, cut the leads to the old and wire in the new with a chocolate block connector or use the crimp connectors supplied with the replacement.
In general you should be careful working on gas appliances, as mistakes could leave them in a dangerous state (though diaphragm replacement isn't too risky IMO)
Your boiler has presumably not been properly serviced for a couple of years, now might be a good time to get it done, it will prevent other common ailments such as hot/cold domestic hot water temperature cycling, wild fluctuations in pressure associated with using the central heating, and it also gives a general safety check. Phone Vokera for a local trained service man. Always use someone familiar with your specific boiler, generalists can be costly and slow as they learn the quirks of your boiler at your expense.
cd
April 2007