My Potterton Profile 100e failed in just the same way on Wednesday night - the overheat cut out had tripped.
I reasoned - with no qualification or experience to support my reasoning - that the boiler was working overtime to cope with the rapidly falling outside temperature with more "on" time than usual. Because of this the latent heat built up more than usual and helped to push the over heat thermostat into tripping out. My solution was to turn down the boiler stat from just over 4 to 3 and a half.
The boiler then would continue to heat the water but its internal temperature would be a few degrees lower - that was my theory.
So far my theory is working - the boiler stayed on without tripping the next night.
Speeding up the pump may have the same effect - some are adjustable - moving the heated water away more quickly-just a guess.
Peccavi
November 2010