Got the same boiler and have had the same problem in the past..
Suggest you try the following;
1- switch to water only. That is heating turned off. Have someone turn on the hot tap and listen/look to see if boiler fires up. (Probably not from what you say)
2- observe the actuating pin that sticks out from the diaphragm assembly. This should move forward and push on the alloy lever that operates the small microswitch at the bottom left corner of the boiler case. If it isn't moving then the diaphragm is knackered.
3-If it is moving does it actually move forward enough to operate the alloy lever? If not again your diaphragm is stuffed.
4- If all of the above seem ok then you may have a faulty microswitch? This can be checked by operating manually with a suitably insulated screwdriver. There is also an adjusting nut at the microswitch end of the alloy lever.
From what you say however I suspect the diaphragm is split. The small quantity of hot water your getting is simply that stored in the heat exchanger/pipes. New ones are around £4. Do a google search for Vokera + diaphragm and make sure you order the correct size. As far as I know they come in small (around 2inch)and large (around 4inch) depending on date of manufacture.
Good idea to buy a couple as they seem to expire every few years.
All of the above of course assumes that, unlike myself, you are competent / trained to carry out the work and naturally if you scald yourself/gas yourself/electrocute yourself or monoxide your family then please don't blame me ;-). Better still call a Corgi engineer if you want to squander £50ish...
Stu
December 2005