Hi Gillian
if problem is connected to the expansion vessel ,what will happen is when heating is on the presure gauge will raise to over 3 bar and release water/presure out of presure release valve then when heating is of it will go back down to .5 bar check to see if this is happening if not sure put a plastic bottle over the end of the discharge pipe outside and see if any water collects
If this is not the case then you do propably have a small leak somewere if you cannot find it add some fernox leak sealer to system which can be injected through the flling loop if you get the tube container type that fits into a silicon gun,this should seal any small leak such as yours
tony
February 2008