From your description the system is getting repeatedly overpressurised. There are two ways that could happen: The filling loop and valve is allowing mains water into the system OR there is an intermnal leak between the mains side and the system.
My guess is a faulty DHW plate heat exchanger or a faulty diverter valve, for starters.
You could have also have faulty or non-pressurised expansion vessel.
You really need to think about getting a gas safe certfied engineer to look at it
XXX
December 2016