Had this problem where the pilot light goes out after around 20 minutes, wasted £50 for a gas engineer to change the thermocouple still the same.
Called him back he then said the Gas Valve unit had gone which was not the case as they generally don't go faulty.
I downloaded & studied the service manual & did the job myself in the end.
This is the way to make sure you cure this problem:
Fit a direct replacement thermocouple or equivalent not the universal type, take the pilot feed pipe loose and blow both ends to clear debris in the pipe, replace the injector pilot jet as it becomes damaged over many years of use.
After all that check the pilot flame.
The pilot flame ideally should be bluish without a yellow tip & approximately 1 inch (25mm) long, the pilot light should also be approximately lapping around the last 10mm of the thermocouple.
You will probably need to adjust the pilot light adjustment screw to achieve a 25mm or 1 inch pilot flame length, it takes quite a bit of screw adjustment to take an effect.
Anything other than a correct pilot flame will burn out the thermocouple within a year or so.
Check the main burner flames, ideally they should settle to bluish flames with some orange tips not yellow, the tips of the flames should be close but not touch or lap the bottom fins of the heat exchanger, if they do you may need to adjust the governor adjustment screw for correct burner pressure.
If all that did not cure the problem only then start to suspect a faulty gas valve unit as they are very expensive.
Remember that for an occasional loss of pilot light can be a downdraught from the flue on a windy day or a vacuum cleaner exhaust blowing under and towards the fire.
Notes:
You must be either a qualified or competent person with sound knowledge when servicing gas back boilers.
You must check for gas soundness after completion with suitable gas leak detector and or appropriate gas liquid spray for leak detection, you must have a carbon monoxide detector in the room of the boiler.
You should inspect the flue and chimney and carry out a smoke bomb test correctly and fire spillage test.
Always refer to the service manual which is available online.
Jeff Ants
December 2016