The key to removing paint stains from fabric is working quickly. If the paint is an emulsion, remove any excess, keep it damp with cold water and wash at the highest possible temperature (following washing instructions). For oil-based paints, dabbing with white spirit will loosen the stain, and then put it into the washing machine as soon as possible.
http://blogs.problemsolved.co.uk/hints_and_tips/january_2008/how-do-i-remove-paint-stains-from-fabric
tradesmen
July 2009