More searching throws up some suggestionbs:
http://www.ultimatehandyman.co.uk/forum1/baxi-combi-105e-water-only-on-but-rads-get-warm-t49846.html
http://community.screwfix.com/threads/combi-boiler-heating-rads-when-on-water-only.134087/
http://www.urbanplumbers.co.uk/baxi-105e-instant-hot-water-problems-boiler-repair-blog/
https://www.superwarm.co.uk/5-common-faults-of-a-baxi-boiler-and-how-to-fix-them/
You will doubtless have already seen much info like this with your own Google searches. It may be more fruitful to post in a dedicated plumbing/heating/boiler forum than on a general purpose site like this one.
acp
July 2017