Possibly an issue with the 3-port valve (Assuming the hot water is a pumped system and not a gravity one).
Similar problem here:
http://www.diynot.com/diy/threads/baxi-wm-30-3rs.391879/
More info
http://blog.superwarm.co.uk/ultimate-guide-to-diagnosing-a-faulty-boiler-diverter-valve/
https://www.youtube.com/watch?v=vFCOmg3GiZQ
XXX
February 2017