Although you have no leaks inside, do you have any outside ?
I had a similar problem where the presure relief valve was leaking, this is connected to a safety discharge pipe that exits through a wall and used the empty boiler too.
This may not apply to all boilers though, but mine was leaking from the discharge pipe. Had to refill it about once a week.
I was lucky that it had not gone, I emptied the system a few times and this cleared the problem, maybe there was dirt or something in the valve.
Keeping figners crossed.
DG
July 2006