I'd be VERY suprised if it was an expansion vessel problem seeing as you've just had the boiler fitted.
As you intimate, the water MUST be going somewhere, try isolating the flow and return CH valves overnight with pressure in the boiler, this will indicate if it's the boiler or the system (ie: pressure stays normal it's the system).
If, as you say, you've just had it fitted, shouldn't the installer be coming back to check it out?
Or is this a self install?
Carefree
August 2010