you need to blow the pressure off on the boiler, and generally done by opening pressure release valve.
p.r.v held open inflate expansion vessel to 1 bar. close prv and top up to 1.5 bar.
notes: prv will probably leak afterwards but sometimes a couple of quick snap shut moves on it before you top up will make sure it seats a bit.
try pressing pin in in vessel valve to see condition of vessel.
nothing out valve-may just need re-charged
water out valve-diaphragm prop shot, new vessel
iain
October 2008