Possibly the expansion vessel membrane has failed.
You should be able to check. There should be a Schrader type valve (Like on a car tyre) visible on the expansion vessel. Press the little pip in the centre (Like you were letting a car tyre down). If any water comes out, you need a new vessel.
A new boiler specific replacement can be pricey. As a less expensive (and more convenient solution for later maintenance) you could get an aftermarket one fitted externally to the boiler (assuming there is somewhere on the return pipe to fit it put of sight).
Remember to pressurise the vessel correctly in line with the boiler instructions before refilling the system :-)
As this is a combi boiler, the other alternative is the secondary heat exchanger feeding the hot water system has an internal leak, feeding mains water into the heating circuit. This is about £100 for parts alone so it would be worth considering getting an engineer to fix the boiler - typical one-off call out is about £300 as the implication of screwing anything else up and recommissioning the system properly are a risk. Worcester Bosch may also offer a basic minimum length service contract for about the same money. I know Glowworm do
XXX
December 2016