I had a similar problem, where the temperature would rise to over 90 degrees and the the burner would stop. Initaially thought it was the divertor valve as Central heating would be on when only the hot water was selected. Turns out there was sediment in the boiler that was restricting the flow. Squeezed the rubber tube inside the boiler and felt the crunch of the sediment. Found this out after power flush was conducted. So check that first, I'd say
Sidder
January 2013