Most recent Vaillants have internal filling loops (except for the Ecotec pro), but as you can't identify your model, it makes it a bit difficult to be more specific.
If you have an external filling loop, it will look something like the diagram on the link
http://www.heatandplumb.com/images/boiler_accessories/mid_product_HPPR10016125.jpg
Carefree
January 2011