hi Dan
When I say thermister, this is what you refer to as the pump over run thermostat. There is one on the DHW flow pipe and one on the pipe that comes out of the main heat exchanger above the burner assembly. They are both the same, you can check they are working correctly by checking there rsistance with an ammeter, the resistance is in the boiler manual. The one on the water to water heat exchanger only regulates the temperature the hot water comes out of the tap, the one that controls the pump over run is the thermister on the main heat exchanger because when the pump runs on after DHW demand is switched off the boiler circulates the excess heat around the radiators. My problem in the end was scale build up in the main heat exchanger so the heat couldn't be removed quick enough. I ended up descaling my system and boiler which fixed my problem. But because it was so severely scaled I used a powerflush acid cleaner and circulated it in my system for two hours using the boiler pump and I fitted a magnaclean.
Andy
November 2010