The Domestic Hot Water ( DHW ) heat exchanger is fractured, allowing mains pressure cold water, normally contained inside the heat exchanger, to continuously leak out into the Central Heating pipework which surrounds it, thereby increasing the system pressure. The pressure relief valve is working as it should, by allowing the resulting dangerous rise in system pressure to be drained off to the outside of the house. Fit a new DHW heat exchanger. ( a simple job )
Frank
March 2010