I have recently had a similar problem - now cured.
The fan would run and the pilot would light eventually but the burner would not burn. To begin with it was perhaps two minutes delay and over time could be as long as two hours before burner ignition. I had a spare PCB and changed it but it did not solve the problem.
The pilot flame was too feeble to properly generate enough heat to tell the PCB to open the main gas valve.
An engineer removed the pilot injector and cleaned it (£35 for cash) and now the pilot flame is good and hot and the delay time is about 5 seconds. The spark electrode now glows bright red when the boiler runs.
This on my Potterton Profile 100e - you don't mention your boiler?
Peccavi
December 2008