because its going out the overflow (pressure relief valve)outside as you said,????
your 3 bar safety valve has opened up either due to yourself over pressurising the boiler or due to a fault like below. now the valve isnt shut 100% due to dirt or similar and is allowing system water out.
boiler cold--guage around 1-1.5bar
boiler with heating on for 15 mins--guage around 2-2.5bar
(normal operation)
if cold is correct then with heating on pressure guage rises to 3+bar then expansion vessel needs recharged or replaced.
just mentioned cos 2 sometimes related.
iain
June 2008