To answer your question. BOTH of the terminals under the plastic cap inside the bonnet of the Citroen Xsara Picasso are POSITIVE!! Yep! the + and the + in a circle are the SAME - POSITIVE.
To jump start the car, connect the POSITIVE of the jump leads to the + in the circle (DEAD battery) the other end of the POSITIVE to the positve of the LIVE battery. Connect the NEGATIVE lead of the jump leads to the NEGATIVE of the LIVE battery and the other end to the BONNET RELEASE CATCH of the Citroen. Start up the car with the LIVE battery - leave running for 2 minutes and then start the Citroen. Once the Citroen has started, switch on the headlights and heater on full blower and the disconnect the jump leads in REVERSE ORDER.
BORNAGAIN
March 2016