Hi Rory,
I am a leadlight teacher from Australia and after reading your question I doubt very much if the problem is caused by hot sun - we too have very hot sun as well.
I would suggest there is another problem. Is your area affected by high winds? I would also need to know if the panel has or more than likely, hasn't any reiforcing internally in the panel. (All leadlights should be reinforced if they are over a certain size.) Is it a door panel and does it suffer slamming in wind?
Of course it is difficult to answer this question with out certain information and you can try the following which may have the answers for you.
I have published leadlight tutorials on HubPages. Google this and have a look at lesson 7 & 8 which may help you.
Best of luck.
John Jackson
January 2011