second Afterthought...
Here's my theory - All of the devices in your house are working fine (will not trip RCD) but two of them when operating simultaneously achieve enough leakage (added together) to trip the RCD.
As the RCD mainly trips out when you are not there, the two devices must be either timer controlled or switched by a thermostat. The CH bolier and associated components - Fan, Zone Valve, Pump, Igniter - will be doing their thing when you are away from home. One or even two of them may be contributing to the fault.
Other appliances that "cycle" on their own are firdges and freezers.
If the fault first appeared soon after a change in one of these areas the nature of the change may be a guide to the solution. If the fault has just materialised without an associated change then the cause may be a deteriorating component.
I am aware that electrolytic capacitors tend to fail over time especially in a warm or hot environment like inside your boiler enclosure - there are several electrolytic capacitors in your CH controls (guessing now) and the cause (one or both) may be there.
You have two devices with high leakage that when operating together trip your RCD. One of them is probably associated with your water boiler, which presumably is left on while you're at work.
A control board for a CH boiler costs over £100 + fitting etc. A set of electrolytic capacitors to replace those on the control board are about £1.50. See...
http://kaijaks.co.uk/blog/nick/2008/02/10/dodgy-old-boiler
Richard Buxton
September 2008